{"created":"2024-11-21T07:42:37.044008+00:00","id":2003169,"links":{},"metadata":{"_buckets":{"deposit":"0f0df720-6cd4-429e-b5a4-f8a15dc2843c"},"_deposit":{"created_by":9,"id":"2003169","owner":"9","owners":[9],"pid":{"revision_id":0,"type":"depid","value":"2003169"},"status":"published"},"_oai":{"id":"oai:wakayama-u.repo.nii.ac.jp:02003169","sets":["1728440704509:1728440822844","1728442251420:1729055465669:1729055584980"]},"author_link":[],"item_1617186331708":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"一次元混合金属錯体[Cu(chxn)_2][PtX_2(chxn)_2]X_4(X=Cl,Br)の原子価構造と鎖上のスピン挙動の研究","subitem_title_language":"ja"},{"subitem_title":"Valence Structures and Spin Dynamics in One-Dimensional Mixed-Metal Complexes, [Cu (chxn)_2] [PtX_2 (chxn)_2]X_4 (X:CI, Br)","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"作成者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"青木, 裕史","creatorNameLang":"ja"},{"creatorName":"AOKI, Hiroshi","creatorNameLang":"en"},{"creatorName":"アオキ, ヒロシ","creatorNameLang":"ja-Kana"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"教育学部","affiliationNameLang":"ja"},{"affiliationName":"Faculty of Education","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"木曽田, 賢治","creatorNameLang":"ja"},{"creatorName":"KISODA, Kenji","creatorNameLang":"en"},{"creatorName":"キソダ, ケンジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"100000590_ja.html","nameIdentifierScheme":"研究者総覧","nameIdentifierURI":"https://researchers.center.wakayama-u.ac.jp/html/100000590_ja.html"},{"nameIdentifier":"read0014032","nameIdentifierScheme":"researchmap","nameIdentifierURI":"https://researchmap.jp/read0014032"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"教育学部","affiliationNameLang":"ja"},{"affiliationName":"Faculty of Education","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"木村, 憲喜","creatorNameLang":"ja"},{"creatorName":"KIMURA, Noriyoshi","creatorNameLang":"en"},{"creatorName":"キムラ, ノリヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"100000629_ja.html","nameIdentifierScheme":"研究者総覧","nameIdentifierURI":"https://researchers.center.wakayama-u.ac.jp/html/100000629_ja.html"},{"nameIdentifier":"read0192168","nameIdentifierScheme":"researchmap","nameIdentifierURI":"https://researchmap.jp/read0192168"}]}]},"item_1617186626617":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"We measured the Raman, UV-visible and ^<13>C CP-MAS NMR spectra of halogen-bridged 1-D Cu-Pt mixed-metal complexes, [Cu (chxn)_2] [PtX_2 (chxn) 2]X_4 (X : Cl and Br), consisting of -X-Cu-X-Pt-X-chain. The Raman spectra showed an overtone progression of symmetric stretching mode of Pt (IV) -Cl atoms and the fine structures with halogen isotopic splitting in Pt-Cl band below ca. 50 K. The broad carbon signals of the ^<13>C NMR spectra observed at room temperature are attributable to strong paramagnetic effect from Cu (II) sites. This result is supported by the weak antiferromagnetic interactions between Cu (II) sites in the chain.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_1617186643794":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"和歌山大学教育学部","subitem_publisher_language":"ja"}]},"item_1617186702042":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_1617186920753":{"attribute_name":"収録物識別子","attribute_value_mlt":[{"subitem_source_identifier":"13424645","subitem_source_identifier_type":"PISSN"},{"subitem_source_identifier":"AN00257977","subitem_source_identifier_type":"NCID"}]},"item_1617187056579":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2005-02-28","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"3","bibliographicPageStart":"1","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"和歌山大学教育学部紀要. 自然科学","bibliographic_titleLang":"ja"},{"bibliographic_title":"Bulletin of the Faculty of Education, Wakayama University. Natural science","bibliographic_titleLang":"en"}]}]},"item_1617265215918":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1617604990215":{"attribute_name":"ファイル","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2011-05-18"}],"displaytype":"detail","filename":"KJ00004292656.pdf","filesize":[{"value":"269.0 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://wakayama-u.repo.nii.ac.jp/record/2003169/files/KJ00004292656.pdf"},"version_id":"c1a78627-275a-4838-a3d7-36879310f737"}]},"item_1623818042585":{"attribute_name":"identifier_registration","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.19002/AN00257977.55.1","subitem_identifier_reg_type":"JaLC"}]},"item_1725499675744":{"attribute_name":"item_1725499675744","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"一次元混合金属錯体[Cu(chxn)_2][PtX_2(chxn)_2]X_4(X=Cl,Br)の原子価構造と鎖上のスピン挙動の研究","item_type_id":"40002","owner":"9","path":["1728440822844","1729055584980"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-11-11"},"publish_date":"2024-11-11","publish_status":"0","recid":"2003169","relation_version_is_last":true,"title":["一次元混合金属錯体[Cu(chxn)_2][PtX_2(chxn)_2]X_4(X=Cl,Br)の原子価構造と鎖上のスピン挙動の研究"],"weko_creator_id":"9","weko_shared_id":-1},"updated":"2025-03-31T04:46:07.744058+00:00"}